This paper is published in Volume-11, Issue-6, 2025
Area
Electrochemical Engineering
Author
Harmaya Thukral
Org/Univ
Oberoi International School, Maharashtra, India
Keywords
Hydrogen Production, Alkaline Electrolysis, Current Density, Faradaic Efficiency, Electrochemical Performance.
Citations
IEEE
Harmaya Thukral. Hydrogen Yield Efficiency Based on Current Density in AWE, International Journal of Advance Research, Ideas and Innovations in Technology, www.IJARIIT.com.
APA
Harmaya Thukral (2025). Hydrogen Yield Efficiency Based on Current Density in AWE. International Journal of Advance Research, Ideas and Innovations in Technology, 11(6) www.IJARIIT.com.
MLA
Harmaya Thukral. "Hydrogen Yield Efficiency Based on Current Density in AWE." International Journal of Advance Research, Ideas and Innovations in Technology 11.6 (2025). www.IJARIIT.com.
Harmaya Thukral. Hydrogen Yield Efficiency Based on Current Density in AWE, International Journal of Advance Research, Ideas and Innovations in Technology, www.IJARIIT.com.
APA
Harmaya Thukral (2025). Hydrogen Yield Efficiency Based on Current Density in AWE. International Journal of Advance Research, Ideas and Innovations in Technology, 11(6) www.IJARIIT.com.
MLA
Harmaya Thukral. "Hydrogen Yield Efficiency Based on Current Density in AWE." International Journal of Advance Research, Ideas and Innovations in Technology 11.6 (2025). www.IJARIIT.com.
Abstract
Hydrogen production through alkaline water electrolysis (AWE) remains one of the most reliable and economically feasible pathways for generating clean hydrogen. However, the efficiency of AWE is strongly influenced by the operating current density, particularly at higher loads, where bubble accumulation, increased overpotential, and mass-transport limitations reduce the practical hydrogen yield. This study examines the effect of varying current density on hydrogen yield efficiency by comparing the experimentally collected hydrogen volume with theoretical values derived from Faraday’s law. Electrolysis was performed using stainless steel electrodes in a 0.50 M NaOH electrolyte over current inputs ranging from 0.10 A to 0.50 A. For each current setting, the corresponding hydrogen volume was measured via the water displacement method, converted to moles using the ideal gas law, and evaluated against the predicted stoichiometric output. The results show a near-linear increase in hydrogen production at lower current densities but a noticeable deviation from ideal Faradaic behaviour at higher currents. Faradaic efficiency decreased from approximately 94% at 0.10 A to around 85% at 0.50 A, confirming that bubble blockage, resistive heating, and kinetic limitations become more pronounced as current density increases. The study provides a clear, empirical relationship between current density and hydrogen yield efficiency in a simple AWE system, offering useful insights for small-scale electrolysis applications and highlighting the practical limitations encountered when transitioning to higher operational loads. Beyond quantifying efficiency trends, this study also demonstrates the importance of understanding electrochemical behaviour when scaling up hydrogen production systems. Since many educational and laboratory AWE setups operate without advanced engineering features—such as forced electrolyte circulation, porous electrodes, or catalytic coatings—the findings provide a realistic baseline for performance expectations in simple electrolyzers. The observations reinforce that while increasing current density boosts hydrogen output, it simultaneously introduces non-idealities that lower conversion efficiency. These insights can support future optimisations in electrode design, electrolyte composition, and cell configuration for improved hydrogen yield in low-cost AWE systems. Overall, the study highlights the value of Faradaic efficiency as a diagnostic tool for evaluating real-world electrolyzer performance. By directly comparing theoretical and experimental hydrogen yields, the method used here provides a simple yet powerful way to identify operational losses without requiring advanced instrumentation. This approach can be applied in future work to assess the influence of factors such as electrode spacing, electrode surface treatment, electrolyte concentration, and temperature on hydrogen output. The findings, therefore, not only document the behaviour of AWE under varying current densities but also establish a practical framework for improving system efficiency in academic, laboratory, and introductory research settings.
